成都气溶胶吸湿性能特征及其与能见度的关系

Characteristics of Aerosol Hygroscopicity in Chengdu and its Relationship with Visibility

  • 摘要: 本文采用吸湿性串联差分式电迁移粒径谱仪(Hygros-copicity Tandem Diferential Mobility Analyzer,H-TDMA)和气溶胶组分监测仪(S-611EG),对成都市2019年1—2月气溶胶粒子吸湿增长因子(GF)、气溶胶液态含水量(ALWC)、气溶胶谱分布(PNSD)、粒子化学组分进行观测,并结合气象要素分析了成都市大气气溶胶吸湿效应及其对能见度的影响。结果表明:(1)成都冬季 40~200 nm的非吸湿模态粒子(GFNH)的吸湿增长因子随粒径增大而减小,强(弱)吸湿模态粒子的吸湿增长因子(GFMH,LH)均随粒径增大而增大,非(弱)吸湿性粒子比例(NFNH,LH)随粒径增大而减少。(2)成都冬季气溶胶液态含水量由爱根核模态和积聚模态粒子占主导,其中爱根核模态对ALWC贡献最大。相对湿度(RH)、细颗粒物(PM2.5)对ALWC的影响力依次降低,高PM2.5且高RH是高ALWC的充分条件。(3)不利气象条件是成都此次雾霾过程的主要成因,低能见度在低RH时由 PM2.5 积累所致,而气溶胶吸湿增长效应在高RH时主导能见度下降。

     

    Abstract: The aerosol particle hygroscopic growth factor (GF), aerosol liquid water content (ALWC), particle number size distribution (PNSD), and particle chemical composition in Chengdu from January to February 2019 were observed by using a Hygroscopic Tandem Differential Mobility Analyzer (H-TDMA) and an aerosol component monitor (S-611EG). Combined with meteorological factors, the hygroscopic effect of atmospheric aerosols in Chengdu and its impact on visibility were analyzed. The results showed that: (1) The hygroscopic growth factor of non-hygroscopic mode particles (GFNH) in the size range of 40–200 nm in Chengdu in winter decreased with increasing particle size, while the hygroscopic growth factors of both strong and weak hygroscopic mode particles (GFMH, LH) increased with increasing particle size, and the proportions of non-hygroscopic and weakly hygroscopic particles (NFNH, LH) decreased with increasing particle size. (2) The aerosol liquid water content in Chengdu in winter was dominated by particles in the Aitken mode and accumulation mode, with the Aitken mode contributing the most to ALWC. The influence of relative humidity (RH) and fine particulate matter (PM2.5) on ALWC decreased in that order, and high PM2.5 combined with high RH was a sufficient condition for high ALWC. (3) Adverse meteorological conditions were the main cause of the haze event in Chengdu. Low visibility resulted from the accumulation of PM2.5 under low RH conditions, while the hygroscopic growth effect of aerosols dominated the visibility reduction under high RH conditions.

     

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